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In the formation of an ordinary agate, it is probable that waters containing silica in solution — derived, perhaps, from the decomposition of some of the silicates in the lava itself — percolated through the rock and deposited a siliceous coating on the interior of the vapour-vesicles.
Variations in the character of the solution or in the conditions of deposition may cause a corresponding variation in the successive layers, so that bands of chalcedony often alternate with layers of crystalline quartz.
Several vapour-vesicles may unite while the rock is still viscous, and thus form a large cavity which may become the home of an agate of exceptional size ; thus a Brazilian geode lined with amethyst and weighing 35 tons was exhibited at the Düsseldorf Exhibition of 1902.
Perhaps the most comprehensive review of agate chemistry is a recent text by Moxon cited below.

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