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Perhaps Grothendieck's deepest single accomplishment is the invention of the étale and l-adic cohomology theories, which explain an observation of André Weil's that there is a deep connection between the topological characteristics of a variety and its diophantine ( number theoretic ) properties.
For example, the number of solutions of an equation over a finite field reflects the topological nature of its solutions over the complex numbers.
Weil realized that to prove such a connection one needed a new cohomology theory, but neither he nor any other expert saw how to do this until such a theory was found by Grothendieck.

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