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Some nonstandard amino acids are not found in proteins.
Examples include lanthionine, 2-aminoisobutyric acid, dehydroalanine, and the neurotransmitter gamma-aminobutyric acid.
Nonstandard amino acids often occur as intermediates in the metabolic pathways for standard amino acids — for example, ornithine and citrulline occur in the urea cycle, part of amino acid catabolism ( see below ).
A rare exception to the dominance of α-amino acids in biology is the β-amino acid beta alanine ( 3-aminopropanoic acid ), which is used in plants and microorganisms in the synthesis of pantothenic acid ( vitamin B < sub > 5 </ sub >), a component of coenzyme A.

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