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Many important proteinogenic and non-proteinogenic amino acids also play critical non-protein roles within the body.
For example the standard glutamic acid ( glutamate ) and the non-standard gamma-amino acid gamma-amino-butyric acid ( GABA ) are respectively the brain's main excitatory and inhibitory neurotransmitters, hydroxyproline-a major component of the connective tissue collagen-is synthesised from proline, the standard amino acid glycine is used to synthesise porphyrins used in red blood cells, and the non-standard carnitine is used in lipid transport.

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