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The true beginning of atomic physics is marked by the discovery of spectral lines and attempts to describe the phenomenon, most notably by Joseph von Fraunhofer.
The study of these lines led to the Bohr atom model and to the birth of quantum mechanics.
In seeking to explain atomic spectra an entirely new mathematical model of matter was revealed.
As far as atoms and their electron shells were concerned, not only did this yield a better overall description, i. e. the atomic orbital model, but it also provided a new theoretical basis for chemistry

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