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Following the ending of rifting in the Late Cretaceous to the early Tertiary, the Big Bend area was subjected to the Laramide orogeny.
This period of ( now east-west ) compression caused the northeast-facing Mesa de Anguila ( an uplifted monocline on the southwest margin of the park ), the southwest-facing Sierra del Carmen – Santiago Mountains ( an uplifted and thrust-faulted monocline that forms the boundary of the park on the east ) and the Tornillo Basin.
During the middle Tertiary most of the volcanic rocks, including the Chisos group, the Pine Canyon caldera complex and the Burro Mesa Formation, formed.

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