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In 2003, Cantrell released her second album, Bittersweet, which peaked at # 37 on the Billboard 200.

The success of ' Bittersweet ' was much greater worldwide than in the U. S. due to the number one single ' Breathe ' which climbed to the top of the charts.

The song became number one without the support of any major radio syndication and eventually was added to major rotation after it had already become independently worldwide.

The record earned Cantrell a Grammy Award nomination for Best R & B Album and entered the Billboard Top R & B / Hip-Hop Albums chart at number eight.

The album produced two hit singles, these being " Breathe " and " Make Me Wanna Scream ", the former being a collaboration with Sean Paul.

" Breathe " peaked at number one for four weeks in the United Kingdom and broke Madonna's song " Lucky Star " single for most played on radio.

It eventually became one of the most successful singles of the year in Europe, Australia, South Africa, and several other countries worldwide.

That same year, Cantrell was to appear in Playboy magazine ( and would have been only the fourth African American woman to appear on the cover ), but decided against it at the last minute because " I felt it was going to make me more of a sex symbol and I didn't want anything to take away from the fact that I can sing ".< ref >