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According to the United States Census Bureau, the town has a total area of, of which is land and is water, comprising 2. 58 % of the town.
The highest point is the summit of Nottingham Mountain, at above sea level, near the town's western border.
Portions of the Pawtuckaway Mountains occupy the eastern border of the town.
Deerfield is primarily drained by the Lamprey and North Branch rivers, within the Piscataqua River ( Coastal ) watershed, while the western edge and northernmost section of town is in the Merrimack River watershed.

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