Page "Diamond-like carbon" Paragraph 10

Within the " cobblestones ", nodules, clusters, or " sponges " ( the volumes in which local bonding is sp < sup > 3 </ sup >) bond angles may be distorted from those found in either pure cubic or hexagonal lattices because of intermixing of the two.

The result is internal ( compressive ) stress that can appear to add to the hardness measured for a sample of DLC.

Hardness is often measured by nanoindentation methods in which a finely pointed stylus of natural diamond is forced into the surface of a specimen.

If the sample is so thin that there is only a single layer of nodules, then the stylus may enter the DLC layer between the hard cobblestones and push them apart without sensing the hardness of the sp < sup > 3 </ sup > bonded volumes.

Measurements would be low.

Conversely, if the probing stylus enters a film thick enough to have several layers of nodules so it cannot be spread laterally, or if it enters on top of a cobblestone in a single layer, then it will measure not only the real hardness of the diamond bonding, but an apparent hardness even greater because the internal compressive stress in those nodules would provide further resistance to penetration of the material by the stylus.

Nanoindentation measurements have reported hardness as great as 50 % more than values for natural crystalline diamond.

Since the stylus is blunted in such cases or even broken, actual numbers for hardness that exceed that of natural diamond are meaningless.

They only show that the hard parts of an optimal ta-C material will break natural diamond rather than the inverse.

Nevertheless, from a practical viewpoint it does not matter how the resistance of a DLC material is developed, it can be harder than natural diamond in usage.

One method of testing the coating hardness is by means of the Persoz pendulum.