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In a vicinal diol, the two hydroxyl groups occupy vicinal positions, that is, they are attached to adjacent atoms.
These compounds are called glycols.
Examples include 1, 2-ethanediol or ethylene glycol HO —( CH < sub > 2 </ sub >)< sub > 2 </ sub >— OH, a common ingredient of antifreeze products.
Another example is propane-1, 2-diol or alpha propylene glycol, HO — CH < sub > 2 </ sub >— CH ( OH )— CH < sub > 3 </ sub > used in the food and medicine industry as well as a relatively non-poisonous antifreeze product.

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