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Reaction with the halogens should readily form the pentahalides, DbX < sub > 5 </ sub >.
The pentachlorides of niobium and tantalum exist as volatile solids or monomeric trigonal bipyramidal molecules in the vapour phase.
Thus, DbCl < sub > 5 </ sub > is expected to be a volatile solid.
Similarly, the pentafluoride, DbF < sub > 5 </ sub >, should be even more volatile.

2.423 seconds.