Page "Gunpowder" Paragraph 86
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Wikipedia
Vibration during transportation could cause the components to separate again, requiring remixing in the field.
Also if the quality of the saltpeter was low ( for instance if it was contaminated with highly hygroscopic calcium nitrate ), or if the powder was simply old ( due to the mildly hygroscopic nature of potassium nitrate ), in humid weather it would need to be redried.
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