Page "Helium" Paragraph 4
from
Wikipedia
Most terrestrial helium present today is created by the natural radioactive decay of heavy radioactive elements ( thorium and uranium ), as the alpha particles emitted by such decays consist of helium-4 nuclei.
This radiogenic helium is trapped with natural gas in concentrations up to 7 % by volume, from which it is extracted commercially by a low-temperature separation process called fractional distillation.
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