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The ability of the director to align along an external field is caused by the electric nature of the molecules.
Permanent electric dipoles result when one end of a molecule has a net positive charge while the other end has a net negative charge.
When an external electric field is applied to the liquid crystal, the dipole molecules tend to orient themselves along the direction of the field.
( In the following diagram, the black arrows represent the electric field vector and the red arrows show the electric force on the molecule.

2.727 seconds.