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The scientific instruments consisted of an ion chamber and Geiger-Müller tube to measure total radiation flux, a proportional radiation counter telescope to measure high energy radiation, a scintillation counter to monitor low-energy radiation, a scintillation spectrometer to study the Earth's ( and possible lunar ) radiation belts, a VLF receiver for natural radio waves, a transponder to study electron density, and part of the flux-gate and search coil magnetometers mounted on the instrument platform.
A plasma probe was mounted on the sphere to measure energy and momentum distribution of protons above a few kilovolts to study the radiation effect of solar flares.
The micrometeorite detector and sun scanner were mounted on the sphere as well.
The only difference between Pioneer P-31 and the earlier Pioneer P-30 was the addition of a solid state detector sensitive to low energy protons on the satellite and an STL-designed rubidium frequency standard experiment placed on a pod attached to the booster.
The total mass of the science package including electronics and power supply was roughly 60 kg.
Total cost of the mission was estimated at 9-10 million dollars.

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