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Unlike the nitrate, the oxide is similar to the corresponding samarium salt and not the neodymium salt.
As-synthesized, e. g. by heating the oxalate, it is a white or lavender-colored powder with disordered structure.
This powder crystallizes in a cubic lattice upon heating to 600 ° C.
Further annealing at 800 ° C and then at 1750 ° C irreversibly transforms it to a monoclinic and hexagonal phases, respectively, and the last two phases can be interconverted by adjusting the annealing time and temperature.

2.084 seconds.