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In 2002, Williams appeared on the track " My Culture " on the 1 Giant Leap album, alongside rapper Maxi Jazz ( which features lyrics from the hidden track " Hello Sir " from Life Thru a Lens ).

Williams also features on a double CD titled Concrete which was released on the same day as Rudebox.

The CD features a concert recorded for the BBC featuring the Pet Shop Boys and Williams singing their classic hit " Jealousy ".

Their joint effort, " She's Madonna ", was released as a single in March 2007.

On 13 August 2007, a Dean Martin duets album was released, on which Williams sings " Please Don't Talk About Me When I'm Gone ".

Most recently it was announced that Williams has recorded what is going to be Mexican singer Thalía's first single from her upcoming English-language album.