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Although no single individual is responsible for the foundation of the United Federation of Planets, the exploratory vessel Enterprise NX-01 was a major catalyst.
Under the command of Captain Jonathan Archer, it helped forge an alliance between the formerly belligerent Vulcan, Andorian, and Tellarite states, and forged a spirit of unity and cooperation in the Alpha Quadrant, culminating in a formal union in 2161.
It was first preceded by the Coalition of Planets, which was mainly opposed by the xenophobic group, Terra Prime.
The Federation was formed largely out of the aftermath of the Earth-Romulan War of the late 2150s ending in 2160, when the founding members saw the need for interstellar unity to prevent the horror of further war.
Archer was one of the individuals who signed the Federation Charter, after giving a historic speech that was still being studied two centuries later.
According to information seen on a viewscreen in a late episode of Star Trek: Enterprise, Jonathan Archer later became the Federation ambassador to Andoria, a Federation Councillor, and President of the United Federation of Planets from 2184 to 2192.

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