At first, the leading personalities of the system were British foreign secretary Lord Castlereagh, Austrian chancellor Klemens Wenzel, Prince von Metternich and Tsar Alexander I of Russia.

At first, the leading personalities of the system were British foreign secretary Lord Castlereagh, Austrian chancellor Klemens von Metternich and Russian czar Alexander I. Charles Maurice de Talleyrand-Périgord of France was largely responsible for quickly returning that country to its place alongside the other major powers in international diplomacy.

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