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Page "Phenols" ¶ 15
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anions and from
This is often incorrectly inferred from the correct fact that in all electrochemical devices negatively charged anions move towards the anode ( hence their name ) and positively charged cations move away from it.
Note: in a galvanic cell, contrary to what occurs in an electrolytic cell, no anions flow to the anode, the internal current being entirely accounted for by the cations flowing away from it ( cf drawing ).
Although positively charged cations always move towards the cathode ( hence their name ) and negatively charged anions move away from it, cathode polarity depends on the device type, and can even vary according to the operating mode.
The ions are described by their oxidation state and their ease of formation can be inferred from the ionization potential ( for cations ) or from the electron affinity ( anions ) of the parent elements.
The carbonate group is structurally a triangle, where a central C < sub > 4 +</ sup > cation is surrounded by three O < sup > 2 -</ sup > anions ; different groups of minerals form from different arrangements of these triangles.
Note that many of the common polyatomic anions are conjugate bases of acids derived from the oxides of non-metallic elements.
The insolubility of certain sodium minerals such as cryolite and feldspar arises from their polymeric anions, which in the case of feldspar is a polysilicate.
However, this is not the full process ; anions must also be transferred from one half-cell to the other.
The anions are released from the other half-cell where a cation is reduced to the metallic state.
A simpler method has been proposed for constructing Lewis structures eliminating the need for electron counting: the atoms are drawn showing the valence electrons, bonds are then formed by pairing up valence electrons of the atoms involved in the bond-making process and anions and cations are formed by adding or removing electrons to / from the appropriate atoms.
The typical resting membrane potential of a cell arises from the separation of potassium ions from intracellular, relatively immobile anions across the membrane of the cell.
The ion-selective membrane ( B ) allows the counterion Na + to freely flow across, but prevents anions such as hydroxide ( OH -) and chloride from diffusing across.
Deionized water, also known as demineralized water ( DI water, DIW or de-ionized water ), is water that has had its mineral ions removed, such as cations from sodium, calcium, iron, and copper, and anions such as chloride and sulfate.
The mechanism involved is that humic acids can fix both anions and cations and eliminate them from root zones.
Complexes derived from noncoordinating anions have been used to catalyze hydrogenation, hydrosilylation, oligomerization, and the living polymerization of olefins.
Noncoordinating anions are important components of many superacids, which result from the combination of Bronsted acids and Lewis acids.
The target analytes ( anions or cations ) are retained on the stationary phase but can be eluted by increasing the concentration of a similarly charged species that will displace the analyte ions from the stationary phase.
In the above wet-cell, sulfate anions move from the cathode to the anode via the salt bridge and the Zn < sup > 2 +</ sup > cations move in the opposite direction to maintain neutrality.
The anions are separated from the metal center
# There, collisions with the gas strip the extra electrons from the anions, and thus make the particle beam neutral.
In addition, electrons with energies < 20 eV are capable of desorbing hydrogen and fluorine anions from the resist, leading to potential damage to the EUV optical system.

anions and by
At the anode, anions ( negative ions ) are forced by the electrical potential to react chemically and give off electrons ( oxidation ) which then flow up and into the driving circuit.
Many inorganic compounds are ionic compounds, consisting of cations and anions joined by ionic bonding.
It can also be calculated using the Born-Landé equation as the sum of the electrostatic potential energy, calculated by summing interactions between cations and anions, and a short range repulsive potential energy term.
All silicate minerals have a base unit of a < sup > 4 -</ sup > silica tetrahedra — that is, a silicon cation coordinated by four oxygen anions, which gives the shape of a tetrahedron.
The solutions contain the coordination complex ( Na ( NH < sub > 3 </ sub >)< sub > 6 </ sub >)< sup >+</ sup >, whose positive charge is counterbalanced by electrons as anions ; cryptands permit the isolation of these complexes as crystalline solids.
Silicate compounds, including the minerals, consist of silicate anions whose charge is balanced by various cations.
The colour of metal ion solutions is strongly affected by the presence of other species, such as certain anions or ligands.
The aqueous chemistry of boron, more conventionally, is characterised by the formation of many different polyborate anions.
* Distal convoluted tubule: Once leaving the loop of Henle the thick ascending limb can optionally reabsorb and re increase the concentration in the nephrons .< ref > Reabsorbing and increasing the concentration is done by optionally absorbing Potassium ( K < sup >+</ sup >) and Hydrogen ( H < sup >+</ sup >) anions, while releasing water and the continued pumping out of Calcium ( Ca < sup >+</ sup >) and salt ( Na < sup >+</ sup > and Chlorine Cl < sup >-</ sup > ions ).
The ideal cubic-symmetry structure has the B cation in 6-fold coordination, surrounded by an octahedron of anions, and the A cation in 12-fold cuboctahedral coordination.
An even more exotic type of perovskite is represented by the mixed oxide-aurides of Cs and Rb, such as Cs < sub > 3 </ sub > AuO, which contain large alkali cations in the traditional " anion " sites, bonded to O < sup > 2 −</ sup > and Au < sup >−</ sup > anions.
Likewise he defined the anode as the electrode to which anions ( negatively charged ions, like chloride ions Cl ) flow, to be oxidized by depositing electrons on the anode.
These radical anions can be prepared by the reduction of an aromatic system such as naphthalene with metallic lithium.
As predicted by VSEPR, chlorate anions have trigonal pyramidal structures.
Final removal of leftover electrolytes is done by passing the water through a tank with ion-exchange resins, which remove any leftover anions or cations and replace them with hydroxyl and hydrogen molecules, respectively, leaving ultrapure water.
Instead the halides are displaced by strong nucleophiles via reactions involving radical anions.
These anions are mostly contributed by protein.
* Active secretion of ( free & protein-bound ) drug by transporters e. g. anions such as urate, penicillin, glucuronide, sulfate conjugates ) or cations such as choline, histamine.
Iron or carbon steel metal exfoliates when oxidized under neutral or alkaline microelectrolytic conditions ; i. e., the iron oxide ( actually " ferric hydroxide " or hydrated iron oxide, also known as rust ) forms by anoxic anodic pits and large cathodic surface, these pits concentrate anions such as sulfate and chloride accelerating the underlying metal to corrosion.

anions and H
Carboxylic acids are typically weak acids, meaning that they only partially dissociate into H < sup >+</ sup > cations and RCOO < sup >–</ sup > anions in neutral aqueous solution.
A metallocene is a compound typically consisting of two cyclopentadienyl anions ( Cp, which is C < sub > 5 </ sub > H < sub > 5 </ sub >< sup >-</ sup >) bound to a metal center ( M ) in the oxidation state II, with the resulting general formula ( C < sub > 5 </ sub > H < sub > 5 </ sub >)< sub > 2 </ sub > M.
Protonation of these polysulfide anions gives the polysulfanes, H < sub > 2 </ sub > S < sub > x </ sub > where x = 2, 3, and 4.
Examples of oxygen nucleophiles are water ( H < sub > 2 </ sub > O ), hydroxide anion, alcohols, alkoxide anions, hydrogen peroxide, and carboxylate anions
Water ionizes into hydronium ( H < sub > 3 </ sub > O ) cations and hydroxyl ( OH ) anions.
These anions are the conjugate bases of the hydrogen polysulfides H < sub > 2 </ sub > S < sub > n </ sub >.
: Triacylglycerol + 2 H < sub > 2 </ sub > O 2-monoacylglycerol + 2 fatty acid anions
Acid salts compounds can act either as an acid or a base: addition of a suitably strong acid will protonate anions, and addition of a suitably strong base will split off H < sup >+</ sup >.
In electrolytic solutions, a very complicated electrical double layer of H < sub > 2 </ sub > O molecules and anions is formed.
* 05. A Carbonates without additional anions, without H < sub > 2 </ sub > O
* 05. B Carbonates with additional anions, without H < sub > 2 </ sub > O
* 08. A Arsenates without additional anions, without H < sub > 2 </ sub > O
* 08. A Vanadates without additional anions, without H < sub > 2 </ sub > O
Likewise, commonly ' measured ' anions include chloride ( Cl < sup >−</ sup >), bicarbonate ( HCO < sub > 3 </ sub >< sup >−</ sup >) and phosphate ( H < sub > 2 </ sub > PO < sub > 4 </ sub >< sup >−</ sup >), while commonly ' unmeasured ' anions include sulfates and a number of serum proteins.

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