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* Premi Guilio Natta e Nicolò Copernico: Tullio Regge, biographical sketch of prize committee member.
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* Chimica, Materiali e Ingegneria Chimica " Giulio Natta " ( Chemistry Materials and Chemical Engineering )
Natta and prize
Natta and member
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Natta and .
German Karl Ziegler, for his discovery of first titanium-based catalysts, and Italian Giulio Natta, for using them to prepare stereo regular polymers from propylene, were awarded the Nobel Prize in Chemistry in 1963.
Ziegler – Natta catalysts have been used in the commercial manufacture of various polyolefins since 1956.
Natta used crystalline α-TiCl < sub > 3 </ sub > in combination with Al ( C < sub > 2 </ sub > H < sub > 5 </ sub >)< sub > 3 </ sub > to produce first isotactic polypropylene.
Natta used first polymerization catalysts based on titanium chlorides to polymerize propylene and other 1-alkenes.
Both isotactic and syndiotactic polypropylene are crystalline, whereas atactic polypropylene, which can also be prepared with special Ziegler – Natta catalysts, is amorphous.
All modern supported Ziegler – Natta catalysts designed for polymerization of propylene and higher 1-alkenes are prepared with TiCl < sub > 4 </ sub > as the active ingredient and MgCl < sub > 2 </ sub > as a support.
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Karl Waldemar Ziegler ( November 26, 1898 – August 12, 1973 ) was a German chemist who won the Nobel Prize in Chemistry in 1963, with Giulio Natta, for work on polymers.
In 1952, Ziegler disclosed his catalyst to the Montecatini Company in Italy, for which Giulio Natta was acting as a consultant.
Natta denoted this class of catalysts as “ Ziegler catalysts ” and became extremely interested in their ability and potential to stereoregularly polymerize α-olefins such as propene.
For their work on the controlled polymerization of hydrocarbons through the use of these novel organometallic catalysts, Karl Ziegler and Giulio Natta shared the 1963 Nobel Prize in Chemistry.
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