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Originally it was thought that the primitive secondary atmosphere contained mostly ammonia and methane.
However, it is likely that most of the atmospheric carbon was CO < sub > 2 </ sub > with perhaps some CO and the nitrogen mostly N < sub > 2 </ sub >.
In practice gas mixtures containing CO, CO < sub > 2 </ sub >, N < sub > 2 </ sub >, etc.
give much the same products as those containing CH < sub > 4 </ sub > and NH < sub > 3 </ sub > so long as there is no O < sub > 2 </ sub >.
The hydrogen atoms come mostly from water vapor.
In fact, in order to generate aromatic amino acids under primitive earth conditions it is necessary to use less hydrogen-rich gaseous mixtures.
Most of the natural amino acids, hydroxyacids, purines, pyrimidines, and sugars have been made in variants of the Miller experiment.

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