Help


[permalink] [id link]
+
Page "Atomic absorption spectroscopy" ¶ 54
from Wikipedia
Edit
Promote Demote Fragment Fix

Some Related Sentences

HR-CS and AAS
The break-through, however, came when the group of Becker-Ross in Berlin, Germany, built a spectrometer entirely designed for HR-CS AAS.
The first commercial equipment for HR-CS AAS was introduced by Analytik Jena ( Jena, Germany ) at the beginning of the 21st century, based on the design proposed by Becker-Ross and Florek.
There are several techniques available to correct for background absorption, and they are significantly different for LS AAS and HR-CS AAS.
It has already been mentioned that in HR-CS AAS lamp flicker noise is eliminated using correction pixels.
In this case HR-CS AAS is offering the possibility to measure correction spectra of the molecule ( s ) that is ( are ) responsible for the background and store them in the computer.
The same algorithm can actually also be used to correct for direct line overlap of two atomic absorption lines, making HR-CS AAS the only AAS technique that can correct for this kind of spectral interference.

AAS and background
Deuterium HCL or even hydrogen HCL and deuterium discharge lamps are used in LS AAS for background correction purposes.
Another source of background absorption, particularly in ET AAS, is scattering of the primary radiation at particles that are generated in the atomization stage, when the matrix could not be removed sufficiently in the pyrolysis stage.
In LS AAS background absorption can only be corrected using instrumental techniques, and all of them are based on two sequential measurements, firstly, total absorption ( atomic plus background ), secondly, background absorption only, and the difference of the two measurements gives the net atomic absorption.
In essence there are three techniques used for background correction in LS AAS:
As measurement of total and background absorption, and correction for the latter, are strictly simultaneous ( in contrast to LS AAS ), even the fastest changes of background absorption, as they may be observed in ET AAS, do not cause any problem.
In addition, as the same algorithm is used for background correction and elimination of lamp noise, the background corrected signals show a much better signal-to-noise ratio compared to the uncorrected signals, which is also in contrast to LS AAS.

AAS and correction
This might sound complex, but first of all the number of di-atomic molecules that can exist at the temperatures of the atomizers used in AAS is relatively small, and second, the correction is performed by the computer within a few seconds.

AAS and is
Atomic absorption spectroscopy ( AAS ) is a spectroanalytical procedure for the quantitative determination of chemical elements employing the absorption of optical radiation ( light ) by free atoms in the gaseous state.
In flame AAS a steady-state signal is generated during the time period when the sample is aspirated.
In ET AAS a transient signal is generated, the area of which is directly proportional to the mass of analyte ( not its concentration ) introduced into the graphite tube.
Its sensitivity is 2 – 3 orders of magnitude higher than that of flame AAS, so that determinations in the low μg L-1 range ( for a typical sample volume of 20µL ) and ng g-1 range ( for a typical sample mass of 1 mg ) can be carried out.
In classical LS AAS, as it has been proposed by Alan Walsh, the high spectral resolution required for AAS measurements is provided by the radiation source itself that emits the spectrum of the analyte in the form of lines that are narrower than the absorption lines.
The advantage of this technique is that only a medium-resolution monochromator is necessary for measuring AAS ; however, it has the disadvantage that usually a separate lamp is required for each element that has to be determined.
In CS AAS, in contrast, a single lamp, emitting a continuum spectrum over the entire spectral range of interest is used for all elements.
When a continuum radiation source is used for AAS, it is necessary to use a high-resolution monochromator, as will be discussed later.
In LS AAS the high resolution that is required for the measurement of atomic absorption is provided by the narrow line emission of the radiation source, and the monochromator simply has to resolve the analytical line from other radiation emitted by the lamp.
Another feature to make LS AAS element-specific is modulation of the primary radiation and the use of a selective amplifier that is tuned to the same modulation frequency, as already postulated by Alan Walsh.
This way any ( unmodulated ) radiation emitted for example by the atomizer can be excluded, which is imperative for LS AAS.
When a continuum radiation source is used for AAS measurement it is indispensable to work with a high-resolution monochromator.
It should also be pointed out that in LS AAS there is no way to correct for ( the rare case of ) a direct overlap of two atomic lines.
This is the oldest and still most commonly used technique, particularly for flame AAS.

AAS and out
As already pointed out above, we have to distinguish between medium-resolution spectrometers that are used for LS AAS and high-resolution spectrometers that are designed for CS AAS.
The Royal Air Force operated out of AAS from early 1998, just before Operation Desert Fox.

AAS and using
Electrothermal AAS ( ET AAS ) using graphite tube atomizers was pioneered by Boris V. L ’ vov at the Saint Petersburg Polytechnical Institute, Russia, since the late 1950s, and further investigated by Hans Massmann at the Institute of Spectrochemistry and Applied Spectroscopy ( ISAS ) in Dortmund, Germany.
* H. Becker-Ross, S. Florek, U. Heitmann, R. Weisse ( 1996 ), Influence of the spectral bandwidth of the spectrometer on the sensitivity using continuum source AAS, Fresenius J. Anal.
There is an increasing trend of using ICP-MS as a tool in speciation analysis, which normally involves a front end chromatograph separation and an elemental selective detector, such as AAS and ICP-MS. For example, ICP-MS may be combined with size exclusion chromatography and quantitative preparative native continuous polyacrylamide gel electrophoresis ( QPNC-PAGE ) for identifying and quantifying native metal cofactor containing proteins in biofluids.
The acid droplets, condensed on the surface, are then analyzed using AAS.

AAS and information
The School of Arts & Sciences offers degree programs in chemical technology ( AAS ), computer science ( AS ), liberal arts ( AA and AS ), and applied mathematics ( BS ) with concentrations in financial science, information science, and natural science.

AAS and from
The so-called Stabilized Temperature Platform Furnace ( STPF ) concept, proposed by Walter Slavin, based on research of Boris L ’ vov, makes ET AAS essentially free from interference.
It shows a very high degree of freedom from interferences, so that ET AAS might be considered the most robust technique available nowadays for the determination of trace elements in complex matrices.
The first major competition was the tremendously popular 1908 All-Alaska Sweepstakes ( AAS ), which was started by Allan " Scotty " Alexander Allan, and ran from Nome to Candle and back.
In 1863, but for a passing interest in the AAS, Chapman retired from public life and for the next two decades, until her death in 1885, she “ savored the perceived success of her cause and, equally, her own role in the victory .”
Throughout his career he played an active role in the development of public policy for the medical sciences in Australia and was a founding member of the Australian Academy of Science ( AAS ), and served as its president from 1965 to 1969.
With a small amount of additional course work, USAMEOS graduates could earn an AAS in Biomedical Equipment Maintenance from Regis University in Denver.
He has been awarded Honorary Doctor of Science Degrees from the College of Charleston, 1994, and Lander University, 1999 ; he has also been awarded the Komarov Certificate for Space Flight Achievement, 1994, the AAS Flight Achievement Award for STS-51, 1994, Aviation Week & Space Technology 1997 Laurel for Achievement in Space, IEEE / ASME Award for Manager of the Year, 1997, and the Space Center Rotary Club Stellar Award for 1998.
From 1973-2004 it was awarded by the American Association of University Women on advice from the AAS.
While Seppala was most famous for participating in the 1925 serum run which saved the city of Nome from a diphtheria epidemic, according to Page " Seppala was picked to represent all mushers ... but it could just as easily have been named after Scotty Allan " ( the founder of the AAS ).
The Library collection of the AAS contains over three million books, pamphlets, newspapers, periodicals, graphic arts materials and manuscripts as well as books from all fifty U. S. states, most of Canada and the British West Indies are included in their repository.
AAS undertakes special efforts to preserve printed records from this time period, as the Society maintains an on-site conservation department with various sewing, cloth, and binding materials to aid in the preservation process.
He received an AAS ( Associates in Applied Sciences ) degree from the University of Kentucky 1992, and has a BS in Computer Science from Florida Atlantic University as well as a CEH certificate.
The idea of founding the organisation was raised at a meeting of the Third World Academy of Sciences 1985 in Trieste, Italy. In 1986 33 scientists from across Africa founded AAS and elected Thomas Resley Odhiambo as first President

1.267 seconds.