# Bond length: Hyperconjugation is suggested as a key factor in shortening of sigma bonds ( σ bonds ).

Hyperconjugation can be used for rationalizing a variety of other chemical phenomena, including the anomeric effect, the gauche effect, the rotational barrier of ethane, the beta-silicon effect, the vibrational frequency of exocyclic carbonyl groups, and the relative stability of substituted carbocations and substituted carbon centred radicals.

Hyperconjugation: a stabilizing overlap between an pi orbital and a sigma orbital.

Hyperconjugation affects several properties.

Within this frame of reference policies appropriate to claims advanced in the name of the Jews depend upon which Jewish identity is involved, as well as upon the nature of the claim, the characteristics of the claimant, the justifications proposed, and the predispositions of the community decision makers who are called upon to act.

The trouble with all these doctrinal quarrels is that we hear only one side of the story: what, in the secret councils of the Kremlin, Molotov had really proposed, we just don't know, and he has had no chance to reply.

It should be kept in mind that the ease or difficulty with which a town or city can convert to the proposed plan is directly dependent upon the financial condition of that town or city.

However, there is a more profound consideration to this proposed merger than profit and loss.

In the 10-year period, it is proposed that insect and disease control on the National Forest System be stepped up to a level of prevention, detection, and control of insect and disease infestations that will substantially reduce the occurrence of large infestations toward the end of the initial period.

It is proposed that in 10 years all commercial timberlands, all critical watersheds, and other lands in the National Forest System developed or proposed for intensive use will be given protection from fire adequate to meet the fire situation in the worst years and under serious peak loads.

Legislation has already been proposed to authorize the sale of these Government-owned systems in Alaska, and its early enactment is desirable.

On the other hand, the new authority of $3,825 million proposed for missile procurement ( excluding research and construction ) in 1961 is $581 million higher than for 1960.

Upon receipt of an application which the Export-Import Bank is prepared to consider, the Export-Import Bank will inform the Department of Economic Affairs of the identity of the applicant, the nature of the proposed business, the amount of the proposed loan, and the general purposes for which the loan proceeds would be expended.

When the Export-Import Bank is prepared to act favorably upon an application, it will so notify the Department of Economic Affairs and will indicate the interest rate and the repayment period which would be used under the proposed loan.

Within sixty days after the receipt of notice that the Export-Import Bank is prepared to act favorably upon an application the Department of Economic Affairs will indicate to the Export-Import Bank whether or not the Department of Economic Affairs has any objection to the proposed loan.

It is proposed that in the future complete sampling censuses be carried out at five-year intervals.

According to the theory proposed, this is a consequence of the severe condition of perceived threat that persists unabated for the anxious child in an ambiguous sort of school environment.

Obviously, the goal here proposed is the guiding principle in Mr. Justice Frankfurter's opinions -- to the extent that Congress leaves the problem to judicial discretion.

Hoping to cut down on such works, Udall had proposed that a politician be at least fifty years departed before he is memorialized.

and to them it will seem insignificant that it is proposed to defeat such causes non-violently.

A technique by which it is proposed to enter with compulsion into the very heart of a man and determine his values may often in fact seem the more unlimited aggression.

Nevertheless, the consequence of the policy proposed is everywhere subtly qualified: it is `` a possible result, however improbable '' ; ;

Ashlag proposed that such a framework is the purpose of creation, and everything that happens is to raise humanity to the level of altruism, love for one another.

Among the proposed etymologies is the Hurrian and Hittite divinity, Aplu, who was widely invoked during the " plague years ".

In music an " answer " ( also known as countersubject ) is the technical name in counterpoint for the repetition or modification by one part or instrument of a theme proposed by another.

It is possible, although highly doubtful, that he killed none at all but merely let his reputation work for him by privately claiming every unsolved murder in the state.

The place is inhabited by several hundred warlike women who are anachronisms of the Twentieth Century -- stone age amazons who live in an all-female, matriarchal society which is self-sufficient ''.

since Bourbon whiskey, though of Kentucky origin, is at least as much favored by liberals in the North as by conservatives in the South.

In fact it has caused us to give serious thought to moving our residence south, because it is not easy for the most objective Southerner to sit calmly by when his host is telling a roomful of people that the only way to deal with Southerners who oppose integration is to send in troops and shoot the bastards down.

But apart from racial problems, the old unreconstructed South -- to use the moderate words favored by Mr. Thomas Griffith -- finds itself unsympathetic to most of what is different about the civilization of the North.

The two main charges levelled against the Bourbons by liberals is that they are racists and social reactionaries.

It became the sole `` subject '' of `` international law '' ( a term which, it is pertinent to remember, was coined by Bentham ), a body of legal principle which by and large was made up of what Western nations could do in the world arena.

Ratified in the Republican Party victory in 1952, the Positive State is now evidenced by political campaigns being waged not on whether but on how much social legislation there should be.

He was, and is, with the RAND Corporation, a nonprofit pool of thinkers financed by the U.S. Air Force.

They are huge areas which have been swept by winds for so many centuries that there is no soil left, but only deep bare ridges fifty or sixty yards apart with ravines between them thirty or forty feet deep and the only thing that moves is a scuttling layer of sand.

It is softened by the saltbush and the bluebush, has a peaceful quality, the hills roll softly.

On Fridays, the day when many Persians relax with poetry, talk, and a samovar, people do not, it is true, stream into Chehel Sotun -- a pavilion and garden built by Shah Abbas 2, in the seventeenth century -- but they do retire into hundreds of pavilions throughout the city and up the river valley, which are smaller, more humble copies of the former.

Poetry in Persian life is far more than a common ground on which -- in a society deeply fissured by antagonisms -- all may stand.

Nostalgic Yankee readers of Erskine Caldwell are today informed by proud Georgians that Tobacco Road is buried beneath a four-lane super highway, over which travel each day suburbanite businessmen more concerned with the Dow-Jones average than with the cotton crop.

All but the most rabid of Confederate flag wavers admit that the Old Southern tradition is defunct in actuality and sigh that its passing was accompanied by the disappearance of many genteel and aristocratic traditions of the reputedly languid ante-bellum way of life.

Westbrook further bemoans the Southern writers' creation of an unreal image of their homeland, which is too readily assimilated by both foreign readers and visiting Yankees: `` Our northerner is suspicious of all this crass evidence ( of urbanization ) presented to his senses.

As his disciples boast, even though his emphasis is elsewhere, Faulkner does show his awareness of the changing order of the South quite keenly, as can be proven by a quick recalling of his Sartoris and Snopes families.

The unit of form is determined subjectively: `` the Heart, by the way of the Breath, to the Line ''.